85Kr测厚源在锂电池极片面密度测量的应用

85Kr Thickness Gauge Source in Measuring the Areal Density of Lithium Battery Electrodes

  • 摘要: 为满足85Kr测厚源在新能源锂电行业的应用,对测厚源在锂电池极片面密度测量方面开展应用研究。比较分析不同规格的85Kr测厚源的源窗材料、源窗厚度、活性区尺寸以及活度大小对β射线输出量的影响,完成在锂电池极片实际生产过程中,85Kr测厚源β射线吸收值的定量标定、温度补偿标定、极片位置补偿标定以及源活度衰减补偿标定,获得极片面密度与β射线吸收值关系曲线,以及极片面密度与温度、极片位置及源活度衰减关系。结果表明,厚度25 μm钛窗,活性区底面积大且高度低,装载活度18.5 GBq的85Kr测厚源具有较大的β射线输出量,重复测量精度0.02%;β射线透射极片后的衰减吸收值与极片面密度的定量线性相关度达0.999;经监控测量间隙的空气温度,可补偿空气密度变化对β射线吸收的影响;极片距离探测器的位置变化与测量面密度呈线性关系,通过测量位置变化实现对测量值的补偿;至少每5 d修正一次空气零点I0,以补偿85Kr测厚源活度衰减引起的测量系统偏差。85Kr测厚源的使用效果能够满足锂电池超级智能制造产线的实际应用需求。

     

    Abstract: In order to meet the widespread application of 85Kr thickness gauge sources in the new energy lithium battery industry, an application study was conducted on the thickness gauge's use in measuring the coating areal density of lithium battery electrodes. The influence of the source window material, thickness, active area, and activity size on the beta ray output of different specifications of 85Kr thickness gauge was compared and analyzed. The quantitative calibration, temperature compensation calibration, position compensation calibration, and source activity decay compensation calibration of the 85Kr thickness gauge's beta ray absorption value in the actual production process of lithium battery electrodes were completed.The relationship curve between the areal density of the electrode and the beta ray absorption value was obtained, as well as the relationship between the surface density of the electrode and temperature, position, and source activity decay. The research results show that The 85Kr thickness gauge source with a thickness of 25 μm titanium window, a large bottom area and low height of the active zone, and a loading activity of 18.5 GBq has a large betaray output, and the repeatable measurement precision is 0.02%; The linear correlation between the attenuated absorption value of the beta ray after the transmission pole piece and the areal density is 0.999. Measuring the air temperature of the gap compensates for the effect of changes in air density on beta ray absorption. The position change of the pole piece distance detector is linearly related to the measured areal density, compensates for the measured areal density by measuring the position of electrodes. Correct I0 at least every 5 days to compensate for the deviation of the measurement system caused by the activity attenuation of the 85Kr thickness gauge source.The thickness gauge using 85Kr as the radiation source can meet the actual application needs of the super intelligent manufacturing line of lithium-ion batteries.

     

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