Abstract:
ON THE ANAEROBIC BIODEGRADATION PATHWAY OF TA BY ~(14)C and ~3H DOUBLE-LABELLING METHODShen Lixian;Liu Mei(Beijing Municipal Research Institute of Environmental Protection,10037)Lin Zhongmin(Beijing Normal Umversity,100875)ABSRACT The mxiture of ~(14)C and ~3H labelled terephthalic acid TA-(Carbonyl-~(14)C)-(aromaticring-~3H)and non-labelled TA are used as the substrate to carry out the anaerobic test.The TA biodegradationprocess and main intermediate products are obtaind by examining the changes of the concentration of~(14)C and ~3H in methane and carbon dioxide and the analytical results of GC/MS.The main in termediatepreducts in the anaerobic reaction are benzoic acid,alkyl-benzenes,C_8-C_(13) saturated hydrocarbons,C_8-C_(12) olefin,cyclanes and small molecules of aldehyde,alcohol,organic acid and ester,etc.Theanaerobic biedegradation path way of TA is explained qualitatively.Key words ~3H ~(14)C double-labelling terephthalic acid an aerobic biodegradation pathway